2∞[Yb2(NH2)2(Pz)4][Yb(NH3)2(Pz)3PzH]: Electride Induced Synthesis of a 2D-Ytterbium-Pyrazolate Network - Research portal of Justus Liebig University Giessen:

Journal article

2∞[Yb2(NH2)2(Pz)4][Yb(NH3)2(Pz)3PzH]: Electride Induced Synthesis of a 2D-Ytterbium-Pyrazolate Network

Authors list: Müller-Buschbaum, K; Quitmann, CC; Zurawski, A

Publication year: 2007

Pages: 813-817

Journal: Monatshefte für Chemie - Chemical Monthly

Volume number: 138

Issue number: 9

ISSN: 0026-9247

DOI Link: https://doi.org/10.1007/s00706-007-0688-0

Publisher: Springer

Abstract:
²_∞[Yb₂(NH₂)₂(Pz)₄][Yb(NH₃)₂(Pz)₃PzH], Pz⁻ = pyrazolate anion, PzH = pyrazole, C₃H₄N₂ is obtained by the reaction of ytterbium metal with pyrazole in liquid ammonia and subsequent increase of the temperature to 200°C resulting in the formation of colorless single crystals of the compound. The X-ray single crystal analysis reveals that the structure consists of ²_∞[Yb₂(NH₂)₂(Pz)₄] planes with neutral [Yb(NH₃)₂(Pz)₃PzH] monomeric molecules that are located between the planes and ytterbium is trivalent. This is the first example of a two-dimensional network structure of an organic amine of the rare earth elements that derives from an electride induced synthesis. The product decomposes under release of ammonia outside its sealed reaction vessel, viz. if the NH₃ pressure is removed.

Authors/Editors

- Uni.-Prof. Dr. Klaus Müller-Buschbaum

Citation Styles

Harvard Citation style: Müller-Buschbaum, K., Quitmann, C. and Zurawski, A. (2007) 2∞[Yb2(NH2)2(Pz)4][Yb(NH3)2(Pz)3PzH]: Electride Induced Synthesis of a 2D-Ytterbium-Pyrazolate Network, Monatshefte für Chemie - Chemical Monthly, 138(9), pp. 813-817. https://doi.org/10.1007/s00706-007-0688-0

APA Citation style: Müller-Buschbaum, K., Quitmann, C., & Zurawski, A. (2007). 2∞[Yb2(NH2)2(Pz)4][Yb(NH3)2(Pz)3PzH]: Electride Induced Synthesis of a 2D-Ytterbium-Pyrazolate Network. Monatshefte für Chemie - Chemical Monthly. 138(9), 813-817. https://doi.org/10.1007/s00706-007-0688-0