Journal article

Publication year: 2007

Pages: 2614-2618

Journal: Journal of Inorganic and General Chemistry

Volume number: 633

Issue number: 15

ISSN: 0044-2313

DOI Link: https://doi.org/10.1002/zaac.200700282

Publisher: Wiley

Abstract: 
Single crystalline transparent pink(infinity)(1)[Ho2Cl6{1,3-Ph(CN)(2)}(3)] (1,3-Ph(CN)2 = 1,3-benzodinitrile, C6H4(CN)(2)) was obtained by the reaction of anhydrous holmium trichloride with a melt of 1,3-benzodinitrile at 175 degrees C. The trichloride structure is broken up by the dinitrile ligands and re-arranged to double strands of edge connected pentagonal bipyramids of chlorine and nitrogen atoms. The structure can be deduced from the PaCl5 structure type by condensation of two PaCl5 strands and exchange of two chlorine atoms with nitrile groups. The double strands exhibit ligand free cavities of 600-800 pm diameter.

Harvard Citation style: Höller, C. and Müller-Buschbaum, K. (2007) 1∞[Ho2Cl6{1,3-Ph(CN)2}3] - Eine zu Doppelsträngen kondensierte Variante der PaCl5‐Struktur in einem Selten‐Erd‐Benzodinitril‐Koordinationspolymer, Zeitschrift für anorganische und allgemeine Chemie = Journal of Inorganic and General Chemistry, 633(15), pp. 2614-2618. https://doi.org/10.1002/zaac.200700282

APA Citation style: Höller, C., & Müller-Buschbaum, K. (2007). 1∞[Ho2Cl6{1,3-Ph(CN)2}3] - Eine zu Doppelsträngen kondensierte Variante der PaCl5‐Struktur in einem Selten‐Erd‐Benzodinitril‐Koordinationspolymer. Zeitschrift für anorganische und allgemeine Chemie = Journal of Inorganic and General Chemistry. 633(15), 2614-2618. https://doi.org/10.1002/zaac.200700282