Journal article

An Oxygen/Chlorine Double-Capped Praseodymium Tetramer Cluster Complex with Thiazole


Authors listDannenbauer, N; Müller-Buschbaum, K

Publication year2013

Pages2737-2740

JournalJournal of Inorganic and General Chemistry

Volume number639

Issue number15

ISSN0044-2313

DOI Linkhttps://doi.org/10.1002/zaac.201300263

PublisherWiley


Abstract
A tetramer cluster complex of the formula [Pr4Cl10(OH)(2)(thz)(8)(H2O)(2)] was prepared constituted by two edge sharing metal triangles coordinated by thiazole (thz) and chloride ligands bent together by opposing (3)-hydroxide and chloride capping for both triangles. The tetramer is the first thiazole complex of a lanthanide ion and shows a previously unknown symmetric capping mode. It co-crystallizes with an anhydrous dimeric complex of the formula [Pr2Cl6(thz)(8)] in equal amounts.



Citation Styles

Harvard Citation styleDannenbauer, N. and Müller-Buschbaum, K. (2013) An Oxygen/Chlorine Double-Capped Praseodymium Tetramer Cluster Complex with Thiazole, Zeitschrift für anorganische und allgemeine Chemie = Journal of Inorganic and General Chemistry, 639(15), pp. 2737-2740. https://doi.org/10.1002/zaac.201300263

APA Citation styleDannenbauer, N., & Müller-Buschbaum, K. (2013). An Oxygen/Chlorine Double-Capped Praseodymium Tetramer Cluster Complex with Thiazole. Zeitschrift für anorganische und allgemeine Chemie = Journal of Inorganic and General Chemistry. 639(15), 2737-2740. https://doi.org/10.1002/zaac.201300263


Last updated on 2025-21-05 at 15:48