Journal article
Authors list: Kraft, A; Roth, P; Schmidt, D; Stangl, J; Müller-Buschbaum, K; Beuerle, F
Publication year: 2016
Pages: 5982-5987
Journal: Chemistry - A European Journal
Volume number: 22
Issue number: 17
ISSN: 0947-6539
DOI Link: https://doi.org/10.1002/chem.201505137
Publisher: Wiley
Abstract:
Hexakis-substituted [60]fullerene adducts with icosahedral symmetry provide an unprecedented scaffold for the spatial arrangement of twelve functional groups with high geometric precision. This unique molecular symmetry identifies such polyfunctional organic building blocks as potential highly connective linkers for coordination polymer and metal-organic framework synthesis. Hereby, the linker exhibits a higher connectivity than the metal ions and with the main connectivity based on the ligand, this can create a new type of inversely cross-linked framework. Two hexakis adducts bearing either twelve glycolic acid or 3-hydroxypropionic acid side chains attached to its malonate units were incorporated as organic connectivity centers in the first fullerene-containing three-dimensional frameworks by coordination with Zn2+.
Citation Styles
Harvard Citation style: Kraft, A., Roth, P., Schmidt, D., Stangl, J., Müller-Buschbaum, K. and Beuerle, F. (2016) Three-Dimensional Metal-Fullerene Frameworks, Chemistry - A European Journal, 22(17), pp. 5982-5987. https://doi.org/10.1002/chem.201505137
APA Citation style: Kraft, A., Roth, P., Schmidt, D., Stangl, J., Müller-Buschbaum, K., & Beuerle, F. (2016). Three-Dimensional Metal-Fullerene Frameworks. Chemistry - A European Journal. 22(17), 5982-5987. https://doi.org/10.1002/chem.201505137
