Utilizing a Metal Melt of Gallium for the Synthesis of the Homoleptic 1, 2,4‐Triazolate Dense Framework 3∞[Ga(Tz)3] - Research portal of Justus Liebig University Giessen:

Journal article

Utilizing a Metal Melt of Gallium for the Synthesis of the Homoleptic 1, 2,4‐Triazolate Dense Framework 3∞[Ga(Tz)3]

Authors list: Rybak, JC; Rekawka, A; Müller-Buschbaum, K

Publication year: 2013

Pages: 2382-2385

Journal: Journal of Inorganic and General Chemistry

Volume number: 639

Issue number: 14

ISSN: 0044-2313

DOI Link: https://doi.org/10.1002/zaac.201300401

Publisher: Wiley

Abstract:
The low melting element gallium was utilized as a metal melt together with the azole 1, 2,4,-1H-triazole for the synthesis of the homoleptic framework (3)[Ga(Tz)(3)], Tz(-) = 1, 2,4-triazolate. The framework is formed at 180 degrees C at the phase border of two liquid phases, gallium and the azole, which do not mix with one another. Thus, 1, 2,4,-1H-triazole is also in molten state. The homoleptic triazolate adopts the CoAs3 structure and a (4, 6) net topology, exhibiting good thermal stability of 440 degrees C.

Authors/Editors

- Uni.-Prof. Dr. Klaus Müller-Buschbaum

Citation Styles

Harvard Citation style: Rybak, J., Rekawka, A. and Müller-Buschbaum, K. (2013) Utilizing a Metal Melt of Gallium for the Synthesis of the Homoleptic 1, 2,4‐Triazolate Dense Framework 3∞[Ga(Tz)3], Zeitschrift für anorganische und allgemeine Chemie = Journal of Inorganic and General Chemistry, 639(14), pp. 2382-2385. https://doi.org/10.1002/zaac.201300401

APA Citation style: Rybak, J., Rekawka, A., & Müller-Buschbaum, K. (2013). Utilizing a Metal Melt of Gallium for the Synthesis of the Homoleptic 1, 2,4‐Triazolate Dense Framework 3∞[Ga(Tz)3]. Zeitschrift für anorganische und allgemeine Chemie = Journal of Inorganic and General Chemistry. 639(14), 2382-2385. https://doi.org/10.1002/zaac.201300401