Journal article

Adsorption of polynuclear aromatic hydrocarbons from aqueous solution: Agrowaste-modified kaolinite vs surfactant modified bentonite


Authors listUnuabonah, EI; Olu-Owolabi, BI; Böhm, L; Düring, RA

Publication year2016

Pages369-376

JournalBulletin of the Chemical Society of Ethiopia

Volume number30

Issue number3

ISSN1011-3924

Open access statusGold

DOI Linkhttps://doi.org/10.4314/bcse.v30i3.5

PublisherChemical Society of Ethiopia


Abstract
The adsorption efficiency of a new hybrid clay adsorbent for polynuclear aromatic hydrocarbons (PAHs) is compared with known modified clay adsorbents. The new hybrid clay adsorbent (HYCA) showed far higher adsorption capacities for the adsorption of various PAH molecules compared with sodium dodecyl sulfate modified and humic acid modified Bentonite clay adsorbents. With the new hybrid clay adsorbent (HYCA), the adsorption of some of the larger PAH molecules was complete in the first 1 h as compared with approximate to 62% and approximate to 76% observed for both humic acid modified and sodium dodecyl sulfate modified Bentonite clay adsorbents respectively. In 24 h adsorption of the PAHs was complete for all adsorbents with HYCA adsorbent showing better efficiency in the removal of the PAH molecules from aqueous solutions. No significant change was observed with increase in time up to 48 h. The adsorption was observed to be more spontaneous with HYCA adsorbent than with either modified Bentonite adsorbents. The enthalpy of adsorption did not follow any specific order and were not consistent for all PAH molecules considered.



Citation Styles

Harvard Citation styleUnuabonah, E., Olu-Owolabi, B., Böhm, L. and Düring, R. (2016) Adsorption of polynuclear aromatic hydrocarbons from aqueous solution: Agrowaste-modified kaolinite vs surfactant modified bentonite, Bulletin of the Chemical Society of Ethiopia, 30(3), pp. 369-376. https://doi.org/10.4314/bcse.v30i3.5

APA Citation styleUnuabonah, E., Olu-Owolabi, B., Böhm, L., & Düring, R. (2016). Adsorption of polynuclear aromatic hydrocarbons from aqueous solution: Agrowaste-modified kaolinite vs surfactant modified bentonite. Bulletin of the Chemical Society of Ethiopia. 30(3), 369-376. https://doi.org/10.4314/bcse.v30i3.5


Last updated on 2025-10-06 at 10:42