Journal article
Authors list: Saito, F; Gerbig, D; Becker, J; Schreiner, PR
Publication year: 2020
Pages: 3895-3899
Journal: Organic Letters
Volume number: 22
Issue number: 10
ISSN: 1523-7060
DOI Link: https://doi.org/10.1021/acs.orglett.0c01184
Publisher: American Chemical Society
Abstract:
We present the absolute configuration (AC) determination of an alkane, trans-perhydroazulene (1), that displays the naturally very common trans fused [5,7] ring system. We outline the first synthesis yielding enantiopure 1 and the application of optical rotatory dispersion (ORD) and vibrational circular dichroism (VCD) techniques. The spectroscopic results are in excellent agreement with the computed ORD at B3LYP/6-311++G(2d,2p) and the computed VCD spectrum at B3LYP/6-311++G(d,p), providing an assignment of the AC as (R,R)-(+)-1.
Citation Styles
Harvard Citation style: Saito, F., Gerbig, D., Becker, J. and Schreiner, P. (2020) Absolute Configuration of trans-Perhydroazulene, Organic Letters, 22(10), pp. 3895-3899. https://doi.org/10.1021/acs.orglett.0c01184
APA Citation style: Saito, F., Gerbig, D., Becker, J., & Schreiner, P. (2020). Absolute Configuration of trans-Perhydroazulene. Organic Letters. 22(10), 3895-3899. https://doi.org/10.1021/acs.orglett.0c01184
