Journalartikel
Autorenliste: Keul, F; Mardyukov, A; Schreiner, PR
Jahr der Veröffentlichung: 2019
Seiten: 25797-25801
Zeitschrift: Physical Chemistry Chemical Physics
Bandnummer: 21
Heftnummer: 46
ISSN: 1463-9076
DOI Link: https://doi.org/10.1039/c9cp05112k
Verlag: Royal Society of Chemistry
Abstract:
The phenyltelluryl radical was prepared by high-vacuum flash pyrolysis of diphenyl ditelluride and was chacracterized by matrix isolation IR and UV/Vis spectroscopy. After doping the matrix with molecular oxygen and allowing bimolecular reactions, the hitherto unkown phenyltelluro peroxy radical formed and was identified via IR spectroscopy. Irradiation with light at lambda = 436 nm leads to isomerization to the thermodynamically more stable novel phenyltelluroyl radical. All experimental findings agree well with density functional theory (UB3LYP/Def2QZVPP and UM06-2X/Def2QZVPP) computations.
Zitierstile
Harvard-Zitierstil: Keul, F., Mardyukov, A. and Schreiner, P. (2019) Spectroscopic identification of the phenyltelluryl radical and its reactivity toward molecular oxygen, Physical Chemistry Chemical Physics, 21(46), pp. 25797-25801. https://doi.org/10.1039/c9cp05112k
APA-Zitierstil: Keul, F., Mardyukov, A., & Schreiner, P. (2019). Spectroscopic identification of the phenyltelluryl radical and its reactivity toward molecular oxygen. Physical Chemistry Chemical Physics. 21(46), 25797-25801. https://doi.org/10.1039/c9cp05112k