Journalartikel

Jahr der Veröffentlichung: 2020

Seiten: 57047-57054

Zeitschrift: ACS Applied Materials & Interfaces

Bandnummer: 12

Heftnummer: 51

ISSN: 1944-8244

DOI Link: https://doi.org/10.1021/acsami.0c16685

Verlag: American Chemical Society

Abstract: 
The thermal stability of cathode active materials (CAMs) is of major importance for the safety of lithium-ion batteries (LIBs). A thorough understanding of how commercially viable layered oxide CAMs behave at the atomic length scale upon heating is indispensable for the further development of LIBs. Here, structural changes of Li(Ni0.85Co0.15Mn0.05)O-2 (NCM851005) at elevated temperatures are studied by in situ aberration-corrected scanning transmission electron microscopy (AC-STEM). Heating NCM851005 inside the microscope under vacuum conditions enables us to observe phase transitions and other structural changes at high spatial resolutions. This has been primarily possible by establishing low-dose electron beam conditions in STEM. Specific focus is put on the evolution of inherent nanopore defects found in the primary grains, which are believed to play an important role in LIB degradation. The onset temperature of structural changes is found to be similar to 175 degrees C, resulting in phase transformation from a layered to a rock-salt-like structure, especially at the internal interfaces, and increasing intragrain inhomogeneity. The reducing environment and heat application lead to the formation and subsequent densification of {003}- and {014}-type facets. In the light of these results, postsynthesis electrode drying processes applied under reducing environment and heat, for example, in the preparation of solid-state batteries, should be re-examined carefully.

Harvard-Zitierstil: Pokle, A., Ahmed, S., Schweidler, S., Bianchini, M., Brezesinski, T., Beyer, A., et al. (2020) In Situ Monitoring of Thermally Induced Effects in Nickel-Rich Layered Oxide Cathode Materials at the Atomic Level, ACS Applied Materials & Interfaces, 12(51), pp. 57047-57054. https://doi.org/10.1021/acsami.0c16685

APA-Zitierstil: Pokle, A., Ahmed, S., Schweidler, S., Bianchini, M., Brezesinski, T., Beyer, A., Janek, J., & Volz, K. (2020). In Situ Monitoring of Thermally Induced Effects in Nickel-Rich Layered Oxide Cathode Materials at the Atomic Level. ACS Applied Materials & Interfaces. 12(51), 57047-57054. https://doi.org/10.1021/acsami.0c16685