Journal article

Publication year: 2020

Pages: 965-965

Journal: Batteries & Supercaps

Volume number: 3

Issue number: 10

DOI Link: https://doi.org/10.1002/batt.202000205

Publisher: Wiley

Abstract: 
The development of advanced Li-ion batteries relies on the implementation of high-capacity Ni-rich layered oxide cathode materials, such as NCM and NCA, among others. However, fast performance decay because of intrinsic chemical and structural instabilities hampers their practical application. Hence, thoroughly understanding degradation processes is crucial to overcome current limitations. To monitor instabilities of electrode materials under realistic operating conditions, the application of nondestructiveoperandotechniques is required. While structural changes of crystalline phases can be studied by X-ray diffraction, microstructural changes (e. g., particle fracture) cannot be easily accessedin situand are therefore mostly investigatedex situ. Here, we use acoustic emission (AE) measurements to probe a potential next-generation cathode material in real-time. Specifically, we focus on LiNiO2(LNO) and demonstrate that AE events in different frequency ranges can be correlated with the formation of the cathode solid-electrolyte interphase and the mechanical degradation during electrochemical cycling.

Harvard Citation style: Schweidler, S., Bianchini, M., Hartmann, P., Brezesinski, T. and Janek, J. (2020) The Sound of Batteries: An Operando Acoustic Emission Study of the LiNiO2 Cathode in Li-Ion Cells, Batteries & Supercaps, 3(10), p. 965. https://doi.org/10.1002/batt.202000205

APA Citation style: Schweidler, S., Bianchini, M., Hartmann, P., Brezesinski, T., & Janek, J. (2020). The Sound of Batteries: An Operando Acoustic Emission Study of the LiNiO2 Cathode in Li-Ion Cells. Batteries & Supercaps. 3(10), 965. https://doi.org/10.1002/batt.202000205