Journal article

Publication year: 2021

Pages: 110518-

Journal: Journal of The Electrochemical Society

Volume number: 168

Issue number: 11

ISSN: 0013-4651

Open access status: Hybrid

DOI Link: https://doi.org/10.1149/1945-7111/ac33e5

Publisher: The Electrochemical Society

Abstract: 
Following the demand for increased energy density of lithium-ion batteries, the Ni content of the Nickel-Cobalt-Manganese oxide (NCM) cathode materials has been increased into the direction of LiNiO2 (LNO), which regained the attention of both industry and academia. To understand the correlations between physicochemical parameters and electrochemical performance of LNO, a calcination study was performed with variation of precursor secondary particle size, maximum calcination temperature and Li stoichiometry. The structural properties of the materials were analyzed by means of powder X-ray diffraction, magnetization measurements and half-cell voltage profiles. All three techniques yield good agreement concerning the quantification of Ni excess in the Li layer (1.6%-3.7%). This study reveals that the number of Li equivalents per Ni is the determining factor concerning the final stoichiometry rather than the calcination temperature within the used calcination parameter space. Contrary to widespread belief, the Ni excess shows no correlation to the 1(st) cycle capacity loss, which indicates that a formerly overlooked physical property of LNO, namely primary particle morphology, has to be considered.

Harvard Citation style: Kurzhals, P., Riewald, F., Bianchini, M., Sommer, H., Gasteiger, H. and Janek, J. (2021) The LiNiO2 Cathode Active Material: A Comprehensive Study of Calcination Conditions and their Correlation with Physicochemical Properties. Part I. Structural Chemistry, Journal of The Electrochemical Society, 168(11), p. 110518. https://doi.org/10.1149/1945-7111/ac33e5

APA Citation style: Kurzhals, P., Riewald, F., Bianchini, M., Sommer, H., Gasteiger, H., & Janek, J. (2021). The LiNiO2 Cathode Active Material: A Comprehensive Study of Calcination Conditions and their Correlation with Physicochemical Properties. Part I. Structural Chemistry. Journal of The Electrochemical Society. 168(11), 110518. https://doi.org/10.1149/1945-7111/ac33e5