Journal article

Generation of Flavor-Active Compounds by Electrochemical Oxidation of (R)-Limonene


Authors listBirk, F; Hausmann, H; Fraatz, MA; Kirste, A; Aust, NC; Pelzer, R; Zorn, H

Publication year2022

Pages7220-7229

JournalJournal of Agricultural and Food Chemistry

Volume number70

Issue number23

DOI Linkhttps://doi.org/10.1021/acs.jafc.2c01301

PublisherAmerican Chemical Society


Abstract

Terpenes may be converted by electrochemical oxidation to various oxidized products with appealing aroma properties. In this study, (R)-limonene was anodically oxidized in the presence of ethanol, and the resulting mixture exhibited a pleasing fruity, herbal, citrus-like, and resinous odor. The aroma-active compounds were purified by means of preparative high-performance liquid chromatography, and their structures were elucidated by means of gas chromatography (GC)–mass spectrometry and nuclear magnetic resonance spectroscopy. In addition, the odor of the isolated compounds was determined by means of GC–olfactometry. Seventeen compounds were isolated, and for only four of them, analytical data had been reported previously in the literature. Furthermore, only for two of the compounds, an odor description had been available in the literature.




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Citation Styles

Harvard Citation styleBirk, F., Hausmann, H., Fraatz, M., Kirste, A., Aust, N., Pelzer, R., et al. (2022) Generation of Flavor-Active Compounds by Electrochemical Oxidation of (R)-Limonene, Journal of Agricultural and Food Chemistry, 70(23), pp. 7220-7229. https://doi.org/10.1021/acs.jafc.2c01301

APA Citation styleBirk, F., Hausmann, H., Fraatz, M., Kirste, A., Aust, N., Pelzer, R., & Zorn, H. (2022). Generation of Flavor-Active Compounds by Electrochemical Oxidation of (R)-Limonene. Journal of Agricultural and Food Chemistry. 70(23), 7220-7229. https://doi.org/10.1021/acs.jafc.2c01301



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