Journal article
Authors list: Peters, B; Santner, S; Donsbach, C; Vöpel, P; Smarsly, B; Dehnen, S
Publication year: 2019
Pages: 5211-5217
Journal: Chemical Science
Volume number: 10
Issue number: 20
ISSN: 2041-6520
eISSN: 2041-6539
Open access status: Gold
DOI Link: https://doi.org/10.1039/c9sc01358j
Publisher: Royal Society of Chemistry
Abstract:
Selective in situ methylation of terminal chalcogenide ligands of molecular chalcogenido metalate anions in ionothermal reactions with alkylimidazolium-based ionic liquids yields a series of organo-functionalized chalcogenido metalate compounds. We present the syntheses and crystal structures of (C(4)C(1)C(1)Im)(4+x)[Sn10S16O4(SMe)(4)][An](x) (1a-1f), (dmmpH)(6)[Mn4Sn4Se13(SeMe)(4)] (2), and (C(n)C(1)Im)(6)[Hg6Te10(TeMe)(2)] (3a, 3b). The methylation was confirmed by Raman spectroscopy, and the optical absorption properties of the methylated compounds were determined and compared to purely inorganic analogs.
Citation Styles
Harvard Citation style: Peters, B., Santner, S., Donsbach, C., Vöpel, P., Smarsly, B. and Dehnen, S. (2019) Ionic liquid cations as methylation agent for extremely weak chalcogenido metalate nucleophiles, Chemical Science, 10(20), pp. 5211-5217. https://doi.org/10.1039/c9sc01358j
APA Citation style: Peters, B., Santner, S., Donsbach, C., Vöpel, P., Smarsly, B., & Dehnen, S. (2019). Ionic liquid cations as methylation agent for extremely weak chalcogenido metalate nucleophiles. Chemical Science. 10(20), 5211-5217. https://doi.org/10.1039/c9sc01358j
