Journalartikel

Jahr der Veröffentlichung: 2021

Seiten: 1139-1144

Zeitschrift: Journal of Inorganic and General Chemistry

Bandnummer: 647

Heftnummer: 11

Open Access Status: Hybrid

DOI Link: https://doi.org/10.1002/zaac.202100048

Verlag: Wiley

Abstract: 

The imine ligand tris(2-(propan-2-ylideneamino)-ethyl)amine (imine₃tren) had been prepared and characterized. The complexes [Na(imine₃tren)(C₃H₆O)]BPh₄, [Cu(imine₃tren)]BPh₄, [Zn(imine₃tren)(CH₂Cl₂)₂](BPh₄)₂ and [Ni(imine₃tren)Br]BPh₄ were synthesized and structurally characterized. In contrast to copper(I) complexes with related tripodal ligands [Cu(imine₃tren)]BPh₄ reacted quite slowly with dioxygen in solution and no “dioxygen adduct” complex could be spectroscopically detected. Cyclic voltammetry of this complex only showed an irreversible oxidation to a copper(II) species.

Harvard-Zitierstil: Schneider, L., Becker, J. and Schindler, S. (2021) Investigations of metal complexes with the tripodal tetradentate ligand tris(2-(propan-2-ylideneamino)ethyl)amine (imine3tren), Zeitschrift für anorganische und allgemeine Chemie = Journal of Inorganic and General Chemistry, 647(11), pp. 1139-1144. https://doi.org/10.1002/zaac.202100048

APA-Zitierstil: Schneider, L., Becker, J., & Schindler, S. (2021). Investigations of metal complexes with the tripodal tetradentate ligand tris(2-(propan-2-ylideneamino)ethyl)amine (imine3tren). Zeitschrift für anorganische und allgemeine Chemie = Journal of Inorganic and General Chemistry. 647(11), 1139-1144. https://doi.org/10.1002/zaac.202100048