Journalartikel

Jahr der Veröffentlichung: 2020

Seiten: 999-1003

Zeitschrift: Israel Journal of Chemistry

Bandnummer: 60

Heftnummer: 10-11

ISSN: 0021-2148

eISSN: 1869-5868

Open Access Status: Hybrid

DOI Link: https://doi.org/10.1002/ijch.201900120

Verlag: Wiley

Abstract: 
A new tripodal imine ligand tris(2-(propan-2-ylideneamino)ethyl)amine (imine(3)tren) was prepared in order to stabilize high valent iron-oxido complexes. Iron complexes were synthesized in template reactions from iron(II) salts, tris(2-aminoethyl)amine (tren) and acetone. Due to the reversibility of the imine formation, complexes with different ligands were obtained depending on the reaction conditions. Three complexes, [Fe(imine(3)tren)(OAc)(2)] (1), [Fe(imine(3)tren)(OAc)]OTf (2) and [(imine(3)tren)(2)Fe-2(F)(2)](SbF6)(2) (3), could be synthesized and structurally characterized. However, reactions with hydrogen peroxide, iodosobenzene or ozone did not lead to any kind of "oxygen adduct" complex that could be spectroscopically observed.

Harvard-Zitierstil: Will, J., Schneider, L., Becker, J., Becker, S., Miska, A., Gawlig, C., et al. (2020) Synthesis and Reactivity of Iron(II) Complexes with a New Tripodal Imine Ligand, Israel Journal of Chemistry, 60(10-11), pp. 999-1003. https://doi.org/10.1002/ijch.201900120

APA-Zitierstil: Will, J., Schneider, L., Becker, J., Becker, S., Miska, A., Gawlig, C., & Schindler, S. (2020). Synthesis and Reactivity of Iron(II) Complexes with a New Tripodal Imine Ligand. Israel Journal of Chemistry. 60(10-11), 999-1003. https://doi.org/10.1002/ijch.201900120