Journalartikel

Jahr der Veröffentlichung: 2020

Seiten: 248-252

Zeitschrift: European Journal of Inorganic Chemistry

Bandnummer: 2020

Heftnummer: 3

ISSN: 1434-1948

eISSN: 1099-0682

Open Access Status: Hybrid

DOI Link: https://doi.org/10.1002/ejic.201901052

Verlag: Wiley-VCH Verlag

Abstract: 
The production of nylon-6.6 is one of the largest scale syntheses in industrial chemistry. The standard procedure is based on an energy consuming low-level conversion of cyclohexane to yield adipic acid in two steps that is converted to nylon-6.6 in a separate step. Therefore, there is a strong intent to optimize the synthetic route in an economic and ecologic matter. In this work, we present a one-pot oxygenation of cyclohexane with hydrogen peroxide and a mu(4)-oxido-copper cluster catalyst to yield dicarboxylic acids with adipic acid as the main product.

Harvard-Zitierstil: Gawlig, C., Schindler, S. and Becker, S. (2020) One-Pot Conversion of Cyclohexane to Adipic Acid Using a µ4-Oxido-Copper Cluster as Catalyst Together with Hydrogen Peroxide, European Journal of Inorganic Chemistry, 2020(3), pp. 248-252. https://doi.org/10.1002/ejic.201901052

APA-Zitierstil: Gawlig, C., Schindler, S., & Becker, S. (2020). One-Pot Conversion of Cyclohexane to Adipic Acid Using a µ4-Oxido-Copper Cluster as Catalyst Together with Hydrogen Peroxide. European Journal of Inorganic Chemistry. 2020(3), 248-252. https://doi.org/10.1002/ejic.201901052