Journalartikel

Copper(I)-catalyzed intramolecular addition of N-chloroamines to double bonds under aprotic conditions. Towards a stereoselective catalytic radical reaction


AutorenlisteGöttlich, R

Jahr der Veröffentlichung2000

Seiten1561-1564

ZeitschriftSynthesis: Journal of Synthetic Organic Chemistry

Bandnummer11

ISSN0039-7881

DOI Linkhttps://doi.org/10.1055/s-2000-7605

VerlagThieme Publishing / Georg Thieme Verlag


Abstract
Copper(I) complexes catalyze the intramolecular addition of N-chloramines to carbon-carbon double bonds under neutral conditions, a reaction that proceeds via a metal complexed aminyl radical. A high diastereoselectivity is obtained in the cyclization step due to the sterically demanding copper complex.



Autoren/Herausgeber




Zitierstile

Harvard-ZitierstilGöttlich, R. (2000) Copper(I)-catalyzed intramolecular addition of N-chloroamines to double bonds under aprotic conditions. Towards a stereoselective catalytic radical reaction, Synthesis: Journal of Synthetic Organic Chemistry, 11, pp. 1561-1564. https://doi.org/10.1055/s-2000-7605

APA-ZitierstilGöttlich, R. (2000). Copper(I)-catalyzed intramolecular addition of N-chloroamines to double bonds under aprotic conditions. Towards a stereoselective catalytic radical reaction. Synthesis: Journal of Synthetic Organic Chemistry. 11, 1561-1564. https://doi.org/10.1055/s-2000-7605


Zuletzt aktualisiert 2025-21-05 um 13:13