Copper(I)-catalyzed intramolecular addition of N-chloroamines to double bonds under aprotic conditions. Towards a stereoselective catalytic radical reaction - Research portal of Justus Liebig University Giessen:

Journal article

Copper(I)-catalyzed intramolecular addition of N-chloroamines to double bonds under aprotic conditions. Towards a stereoselective catalytic radical reaction

Authors list: Göttlich, R

Publication year: 2000

Pages: 1561-1564

Journal: Synthesis: Journal of Synthetic Organic Chemistry

Volume number: 11

ISSN: 0039-7881

DOI Link: https://doi.org/10.1055/s-2000-7605

Publisher: Thieme Publishing / Georg Thieme Verlag

Abstract:
Copper(I) complexes catalyze the intramolecular addition of N-chloramines to carbon-carbon double bonds under neutral conditions, a reaction that proceeds via a metal complexed aminyl radical. A high diastereoselectivity is obtained in the cyclization step due to the sterically demanding copper complex.

Authors/Editors

- Uni.-Prof. Dr. Richard Göttlich

Citation Styles

Harvard Citation style: Göttlich, R. (2000) Copper(I)-catalyzed intramolecular addition of N-chloroamines to double bonds under aprotic conditions. Towards a stereoselective catalytic radical reaction, Synthesis: Journal of Synthetic Organic Chemistry, 11, pp. 1561-1564. https://doi.org/10.1055/s-2000-7605

APA Citation style: Göttlich, R. (2000). Copper(I)-catalyzed intramolecular addition of N-chloroamines to double bonds under aprotic conditions. Towards a stereoselective catalytic radical reaction. Synthesis: Journal of Synthetic Organic Chemistry. 11, 1561-1564. https://doi.org/10.1055/s-2000-7605