Journalartikel
Autorenliste: Zweidinger, S; Crihan, D; Knapp, M; Hofmann, JP; Seitsonen, AP; Weststrate, CJ; Lundgren, E; Andersen, JN; Over, H
Jahr der Veröffentlichung: 2008
Seiten: 9966-9969
Zeitschrift: Journal of Physical Chemistry C
Bandnummer: 112
Heftnummer: 27
DOI Link: https://doi.org/10.1021/jp803346q
Verlag: American Chemical Society
High-resolution core-level shift spectroscopy and temperature-programmed reaction experiments together with density functional theory calculations reveal that the oxidation of HCl with oxygen producing Cl2 and water proceeds on the chlorine-stabilized RuO2(110) surface via a one-dimensional Langmuir−Hinshelwood mechanism. The recombination of two adjacent chlorine atoms on the catalyst’s surface constitutes the rate-determining step in this novel Deacon-like process.
Abstract:
Zitierstile
Harvard-Zitierstil: Zweidinger, S., Crihan, D., Knapp, M., Hofmann, J., Seitsonen, A., Weststrate, C., et al. (2008) Reaction Mechanism of the Oxidation of HCl over RuO2(110), Journal of Physical Chemistry C, 112(27), pp. 9966-9969. https://doi.org/10.1021/jp803346q
APA-Zitierstil: Zweidinger, S., Crihan, D., Knapp, M., Hofmann, J., Seitsonen, A., Weststrate, C., Lundgren, E., Andersen, J., & Over, H. (2008). Reaction Mechanism of the Oxidation of HCl over RuO2(110). Journal of Physical Chemistry C. 112(27), 9966-9969. https://doi.org/10.1021/jp803346q
