Journal article

Reaction Mechanism of the Oxidation of HCl over RuO2(110)


Authors listZweidinger, S; Crihan, D; Knapp, M; Hofmann, JP; Seitsonen, AP; Weststrate, CJ; Lundgren, E; Andersen, JN; Over, H

Publication year2008

Pages9966-9969

JournalJournal of Physical Chemistry C

Volume number112

Issue number27

DOI Linkhttps://doi.org/10.1021/jp803346q

PublisherAmerican Chemical Society


Abstract

High-resolution core-level shift spectroscopy and temperature-programmed reaction experiments together with density functional theory calculations reveal that the oxidation of HCl with oxygen producing Cl2 and water proceeds on the chlorine-stabilized RuO2(110) surface via a one-dimensional Langmuir−Hinshelwood mechanism. The recombination of two adjacent chlorine atoms on the catalyst’s surface constitutes the rate-determining step in this novel Deacon-like process.




Authors/Editors




Citation Styles

Harvard Citation styleZweidinger, S., Crihan, D., Knapp, M., Hofmann, J., Seitsonen, A., Weststrate, C., et al. (2008) Reaction Mechanism of the Oxidation of HCl over RuO2(110), Journal of Physical Chemistry C, 112(27), pp. 9966-9969. https://doi.org/10.1021/jp803346q

APA Citation styleZweidinger, S., Crihan, D., Knapp, M., Hofmann, J., Seitsonen, A., Weststrate, C., Lundgren, E., Andersen, J., & Over, H. (2008). Reaction Mechanism of the Oxidation of HCl over RuO2(110). Journal of Physical Chemistry C. 112(27), 9966-9969. https://doi.org/10.1021/jp803346q


Last updated on 2025-21-05 at 13:16