Journalartikel

Jahr der Veröffentlichung: 2008

Seiten: 2131-2134

Zeitschrift: Angewandte Chemie International Edition

Bandnummer: 47

Heftnummer: 11

DOI Link: https://doi.org/10.1002/anie.200705124

Verlag: Wiley

Abstract: 

Selective substitution: In the oxidation of HCl with oxygen to give Cl2 and water, RuO2(110) serves as a stable, active model catalyst for the Sumitomo process (see picture; Ru in red and blue). The stability of the catalyst is related to the selective replacement of undercoordinated bridging surface O atoms (Obr) by Cl atoms (Clbr). The chlorination of RuO2(110) is self‐limiting, in that chlorine incorporation terminates when all bridging O atoms are replaced.

Harvard-Zitierstil: Crihan, D., Knapp, M., Zweidinger, S., Lundgren, E., Weststrate, C., Andersen, J., et al. (2008) Stable Deacon Process for HCl Oxidation over RuO2, Angewandte Chemie International Edition, 47(11), pp. 2131-2134. https://doi.org/10.1002/anie.200705124

APA-Zitierstil: Crihan, D., Knapp, M., Zweidinger, S., Lundgren, E., Weststrate, C., Andersen, J., Seitsonen, A., & Over, H. (2008). Stable Deacon Process for HCl Oxidation over RuO2. Angewandte Chemie International Edition. 47(11), 2131-2134. https://doi.org/10.1002/anie.200705124