Journal article

Stable Deacon Process for HCl Oxidation over RuO2


Authors listCrihan, D; Knapp, M; Zweidinger, S; Lundgren, E; Weststrate, CJ; Andersen, JN; Seitsonen, AP; Over, H

Publication year2008

Pages2131-2134

JournalAngewandte Chemie International Edition

Volume number47

Issue number11

DOI Linkhttps://doi.org/10.1002/anie.200705124

PublisherWiley


Abstract

Selective substitution: In the oxidation of HCl with oxygen to give Cl2 and water, RuO2(110) serves as a stable, active model catalyst for the Sumitomo process (see picture; Ru in red and blue). The stability of the catalyst is related to the selective replacement of undercoordinated bridging surface O atoms (Obr) by Cl atoms (Clbr). The chlorination of RuO2(110) is self‐limiting, in that chlorine incorporation terminates when all bridging O atoms are replaced.




Authors/Editors




Citation Styles

Harvard Citation styleCrihan, D., Knapp, M., Zweidinger, S., Lundgren, E., Weststrate, C., Andersen, J., et al. (2008) Stable Deacon Process for HCl Oxidation over RuO2, Angewandte Chemie International Edition, 47(11), pp. 2131-2134. https://doi.org/10.1002/anie.200705124

APA Citation styleCrihan, D., Knapp, M., Zweidinger, S., Lundgren, E., Weststrate, C., Andersen, J., Seitsonen, A., & Over, H. (2008). Stable Deacon Process for HCl Oxidation over RuO2. Angewandte Chemie International Edition. 47(11), 2131-2134. https://doi.org/10.1002/anie.200705124


Last updated on 2025-21-05 at 13:16