Journalartikel

Jahr der Veröffentlichung: 2013

Seiten: 9467-9469

Zeitschrift: Chemical Communications

Bandnummer: 49

Heftnummer: 82

ISSN: 1359-7345

Open Access Status: Hybrid

DOI Link: https://doi.org/10.1039/C3CC45379K

Verlag: Royal Society of Chemistry

Abstract: 

The atmospherically highly relevant methylsulfinyl radical CH₃(O)S˙
was generated thermally under flash pyrolysis conditions and isolated
in Ar matrices at 10 K; the allyl radical is a byproduct. CH₃(O)S˙ and its D₃- and ¹³C-isotopologues were characterized through the excellent agreement between experimental and computed IR and UV/Vis spectra.

Harvard-Zitierstil: Reisenauer, H., Romanski, J., Mloston, G. and Schreiner, P. (2013) Matrix isolation and spectroscopic properties of the methylsulfinyl radical CH3(O)S˙, Chemical Communications, 49(82), pp. 9467-9469. https://doi.org/10.1039/C3CC45379K

APA-Zitierstil: Reisenauer, H., Romanski, J., Mloston, G., & Schreiner, P. (2013). Matrix isolation and spectroscopic properties of the methylsulfinyl radical CH3(O)S˙. Chemical Communications. 49(82), 9467-9469. https://doi.org/10.1039/C3CC45379K