Matrix isolation and spectroscopic properties of the methylsulfinyl radical CH3(O)S˙ - Research portal of Justus Liebig University Giessen:

Journal article

Matrix isolation and spectroscopic properties of the methylsulfinyl radical CH3(O)S˙

Authors list: Reisenauer, HP; Romanski, J; Mloston, G; Schreiner, PR

Publication year: 2013

Pages: 9467-9469

Journal: Chemical Communications

Volume number: 49

Issue number: 82

ISSN: 1359-7345

Open access status: Hybrid

DOI Link: https://doi.org/10.1039/C3CC45379K

Publisher: Royal Society of Chemistry

Abstract:

The atmospherically highly relevant methylsulfinyl radical CH₃(O)S˙
was generated thermally under flash pyrolysis conditions and isolated
in Ar matrices at 10 K; the allyl radical is a byproduct. CH₃(O)S˙ and its D₃- and ¹³C-isotopologues were characterized through the excellent agreement between experimental and computed IR and UV/Vis spectra.

Authors/Editors

- Uni.-Prof. Dr. Peter Richard Schreiner, PhD

Citation Styles

Harvard Citation style: Reisenauer, H., Romanski, J., Mloston, G. and Schreiner, P. (2013) Matrix isolation and spectroscopic properties of the methylsulfinyl radical CH3(O)S˙, Chemical Communications, 49(82), pp. 9467-9469. https://doi.org/10.1039/C3CC45379K

APA Citation style: Reisenauer, H., Romanski, J., Mloston, G., & Schreiner, P. (2013). Matrix isolation and spectroscopic properties of the methylsulfinyl radical CH3(O)S˙. Chemical Communications. 49(82), 9467-9469. https://doi.org/10.1039/C3CC45379K

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