Journal article

Publication year: 2010

Pages: 2132-2137

Journal: European Journal of Organic Chemistry

Volume number: 2010

Issue number: 11

DOI Link: https://doi.org/10.1002/ejoc.200901440

Publisher: Wiley

Abstract: 

The products of the gas‐phase pyrolysis of two regioisomeric 1,2,4‐trithiolane S‐oxides
were collected in an argon matrix at 10 K and studied by means of
spectroscopic as well as computational methods. Whereas the main
products of the pyrolysis of the “symmetrical” S‐oxide were identified asthioformaldehyde S‐oxide and thioformaldehyde S‐sulfide, the “non‐symmetrical” S‐oxide gave predominantly dithioformic acid, which exists as a mixture of s‐cis and s‐trans conformers. We present a rationalization of the reaction pathways including density functional theory computations.

Harvard Citation style: Mloston, G., Romanski, J., McKee, M., Reisenauer, H. and Schreiner, P. (2010) Thermal Reactions of Regioisomeric 1,2,4‐Trithiolane S‐Oxides, European Journal of Organic Chemistry, 2010(11), pp. 2132-2137. https://doi.org/10.1002/ejoc.200901440

APA Citation style: Mloston, G., Romanski, J., McKee, M., Reisenauer, H., & Schreiner, P. (2010). Thermal Reactions of Regioisomeric 1,2,4‐Trithiolane S‐Oxides. European Journal of Organic Chemistry. 2010(11), 2132-2137. https://doi.org/10.1002/ejoc.200901440