Journal article

Publication year: 2008

Pages: 7071-7074

Journal: Angewandte Chemie International Edition

Volume number: 47

Issue number: 37

DOI Link: https://doi.org/10.1002/anie.200802105

Publisher: Wiley

Abstract: 

Out and about: CO₂ extrusion from simple α‐keto
carboxylic acids can be used to prepare hitherto unknown
hydroxycarbenes. High‐vacuum flash pyrolysis of oxalic acid or its
monomethyl ester enabled the preparation and characterization of
dihydroxy‐ (1) and hydroxymethoxycarbene, respectively, both of
which are stabilized through π‐type out‐of‐plane and in‐plane
σ conjugation (the HOMO of s‐trans,s‐trans‐1 is shown).

Harvard Citation style: Schreiner, P. and Reisenauer, H. (2008) Spectroscopic Identification of Dihydroxycarbene, Angewandte Chemie International Edition, 47(37), pp. 7071-7074. https://doi.org/10.1002/anie.200802105

APA Citation style: Schreiner, P., & Reisenauer, H. (2008). Spectroscopic Identification of Dihydroxycarbene. Angewandte Chemie International Edition. 47(37), 7071-7074. https://doi.org/10.1002/anie.200802105