Journalartikel

Jahr der Veröffentlichung: 2008

Seiten: 2998-3003

Zeitschrift: European Journal of Organic Chemistry

Bandnummer: 2008

Heftnummer: 17

DOI Link: https://doi.org/10.1002/ejoc.200800023

Verlag: Wiley

Abstract: 

The flash‐vacuum pyrolysis of selected dispirodicycloaliphatic
1,2,4‐trithiolanes was studied by using matrix isolation techniques. The
formation of thiosulfines and dithiiranes along with the corresponding
thioketones was detected spectroscopically and confirmed by comparison
with computed spectra. In the case of tetramethylcyclobutanone
1,2,4‐trithiolane, the thermal formation of the dithiolactone was
observed. Pyrolysis of the (dichloro)tetramethylcyclobutane derivative
resulted only in the formation of a mixture of the thiosulfine and
dithiirane. In this case, conversion into the corresponding
dithiolactone could be achieved photochemically. The dispirodiadamantane
derivative gave a mixture of the respective thiosulfine and dithiirane
but no dithiolactone could be detected in the mixture.

Harvard-Zitierstil: Romanski, J., Reisenauer, H., Petzold, H., Weigand, W., Schreiner, P. and Mloston, G. (2008) Generation and Rearrangement of Some Spirocycloaliphatic Thiosulfines and Dithiiranes, European Journal of Organic Chemistry, 2008(17), pp. 2998-3003. https://doi.org/10.1002/ejoc.200800023

APA-Zitierstil: Romanski, J., Reisenauer, H., Petzold, H., Weigand, W., Schreiner, P., & Mloston, G. (2008). Generation and Rearrangement of Some Spirocycloaliphatic Thiosulfines and Dithiiranes. European Journal of Organic Chemistry. 2008(17), 2998-3003. https://doi.org/10.1002/ejoc.200800023