Journalartikel

Silicon-(Thio)urea Lewis Acid Catalysis


AutorenlisteHrdina, R; Müller, CE; Wende, RC; Lippert, KM; Benassi, M; Spengler, B; Schreiner, PR

Jahr der Veröffentlichung2011

Seiten7624-7627

ZeitschriftJournal of the American Chemical Society

Bandnummer133

Heftnummer20

ISSN0002-7863

DOI Linkhttps://doi.org/10.1021/ja110685k

VerlagAmerican Chemical Society


Abstract
We present a new class of catalysts based on the combination of N,N'-diaryl(thio)ureas and weak silicon Lewis acids (e.g., SiCl(4)). Such silicon-(thio)urea catalysts effectively catalyze the stereospecific rearrangement of epoxides to quaternary carbaldehydes.



Zitierstile

Harvard-ZitierstilHrdina, R., Müller, C., Wende, R., Lippert, K., Benassi, M., Spengler, B., et al. (2011) Silicon-(Thio)urea Lewis Acid Catalysis, Journal of the American Chemical Society, 133(20), pp. 7624-7627. https://doi.org/10.1021/ja110685k

APA-ZitierstilHrdina, R., Müller, C., Wende, R., Lippert, K., Benassi, M., Spengler, B., & Schreiner, P. (2011). Silicon-(Thio)urea Lewis Acid Catalysis. Journal of the American Chemical Society. 133(20), 7624-7627. https://doi.org/10.1021/ja110685k


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