Journalartikel

Jahr der Veröffentlichung: 2008

Seiten: 9612-9623

Zeitschrift: Inorganic Chemistry

Bandnummer: 47

Heftnummer: 20

ISSN: 0020-1669

DOI Link: https://doi.org/10.1021/ic800244g

Verlag: American Chemical Society

Abstract: 
Copper(II) complexes of the ligand 1,n-bis[bis(2-pyridylmethyl)amino]benzene with n = 2-4 (1,n-tpbd) and its mononuclear derivative bis(2-pyridylmethyl)aniline (phbpa) were synthesized and structurally characterized. Magnetic measurements and DFT calculations were performed on [CuCl2(phbpa)], [Cu2Cl4(1,3-tpbd)], [(Cu2Cl2(ClO4)(1,3-tpbd))Cl(Cu2Cl2(OH2)(1,3-tpbd))](ClO4)2, and [Cu2(OH2)2(S2O6)(1,3-tpbd)]S2O6, and the exchange-polarization mechanism was successfully demonstrated.

Harvard-Zitierstil: Turba, S., Walter, O., Schindler, S., Nielsen, L., Hazell, A., McKenzie, C., et al. (2008) Syntheses, structures, and properties of copper(II) complexes of bis(2-pyridylmethyl) derivatives of o-, m-, and p-phenylenediamine and aniline, Inorganic Chemistry, 47(20), pp. 9612-9623. https://doi.org/10.1021/ic800244g

APA-Zitierstil: Turba, S., Walter, O., Schindler, S., Nielsen, L., Hazell, A., McKenzie, C., Lloret, F., Cano, J., & Julve, M. (2008). Syntheses, structures, and properties of copper(II) complexes of bis(2-pyridylmethyl) derivatives of o-, m-, and p-phenylenediamine and aniline. Inorganic Chemistry. 47(20), 9612-9623. https://doi.org/10.1021/ic800244g