Journal article

Syntheses, structures, and properties of copper(II) complexes of bis(2-pyridylmethyl) derivatives of o-, m-, and p-phenylenediamine and aniline


Authors listTurba, S; Walter, O; Schindler, S; Nielsen, LP; Hazell, A; McKenzie, CJ; Lloret, F; Cano, J; Julve, M

Publication year2008

Pages9612-9623

JournalInorganic Chemistry

Volume number47

Issue number20

ISSN0020-1669

DOI Linkhttps://doi.org/10.1021/ic800244g

PublisherAmerican Chemical Society


Abstract
Copper(II) complexes of the ligand 1,n-bis[bis(2-pyridylmethyl)amino]benzene with n = 2-4 (1,n-tpbd) and its mononuclear derivative bis(2-pyridylmethyl)aniline (phbpa) were synthesized and structurally characterized. Magnetic measurements and DFT calculations were performed on [CuCl2(phbpa)], [Cu2Cl4(1,3-tpbd)], [(Cu2Cl2(ClO4)(1,3-tpbd))Cl(Cu2Cl2(OH2)(1,3-tpbd))](ClO4)2, and [Cu2(OH2)2(S2O6)(1,3-tpbd)]S2O6, and the exchange-polarization mechanism was successfully demonstrated.



Citation Styles

Harvard Citation styleTurba, S., Walter, O., Schindler, S., Nielsen, L., Hazell, A., McKenzie, C., et al. (2008) Syntheses, structures, and properties of copper(II) complexes of bis(2-pyridylmethyl) derivatives of o-, m-, and p-phenylenediamine and aniline, Inorganic Chemistry, 47(20), pp. 9612-9623. https://doi.org/10.1021/ic800244g

APA Citation styleTurba, S., Walter, O., Schindler, S., Nielsen, L., Hazell, A., McKenzie, C., Lloret, F., Cano, J., & Julve, M. (2008). Syntheses, structures, and properties of copper(II) complexes of bis(2-pyridylmethyl) derivatives of o-, m-, and p-phenylenediamine and aniline. Inorganic Chemistry. 47(20), 9612-9623. https://doi.org/10.1021/ic800244g


Last updated on 2025-21-05 at 13:23