Journalartikel

Jahr der Veröffentlichung: 2011

Seiten: 5255-5260

Zeitschrift: European Journal of Organic Chemistry

Bandnummer: 2011

Heftnummer: 27

DOI Link: https://doi.org/10.1002/ejoc.201100783

Verlag: Wiley

Abstract: 

Treatment of [2‐(2‐bromophenyl)allyl]trimethylsilane with tBuLi in
THF at –78 °C resulted in the rapid migration of the trimethylsilyl
group to afford an allylic organolithium that can be easily trapped by a
wide range of electrophiles. This is a rare example of a synthetically
useful and efficientcarbon‐to‐carbon migration of a silicon group and
represents a new approach to allylic organolithium species using anion
relay chemistry.

Harvard-Zitierstil: Zheng, P., Cai, Z., A, G., Rooshenas, P., Schreiner, P. and Harmata, M. (2011) Carbon‐to‐Carbon Anion Relay Chemistry: Facile Generation of Substituted Allyllithium Species, European Journal of Organic Chemistry, 2011(27), pp. 5255-5260. https://doi.org/10.1002/ejoc.201100783

APA-Zitierstil: Zheng, P., Cai, Z., A, G., Rooshenas, P., Schreiner, P., & Harmata, M. (2011). Carbon‐to‐Carbon Anion Relay Chemistry: Facile Generation of Substituted Allyllithium Species. European Journal of Organic Chemistry. 2011(27), 5255-5260. https://doi.org/10.1002/ejoc.201100783