Journal article
Authors list: Zheng, P; Cai, Z; A, Garimallaprabhakaran; Rooshenas, P; Schreiner, PR; Harmata, M
Publication year: 2011
Pages: 5255-5260
Journal: European Journal of Organic Chemistry
Volume number: 2011
Issue number: 27
DOI Link: https://doi.org/10.1002/ejoc.201100783
Publisher: Wiley
Treatment of [2‐(2‐bromophenyl)allyl]trimethylsilane with tBuLi in
Abstract:
THF at –78 °C resulted in the rapid migration of the trimethylsilyl
group to afford an allylic organolithium that can be easily trapped by a
wide range of electrophiles. This is a rare example of a synthetically
useful and efficientcarbon‐to‐carbon migration of a silicon group and
represents a new approach to allylic organolithium species using anion
relay chemistry.
Citation Styles
Harvard Citation style: Zheng, P., Cai, Z., A, G., Rooshenas, P., Schreiner, P. and Harmata, M. (2011) Carbon‐to‐Carbon Anion Relay Chemistry: Facile Generation of Substituted Allyllithium Species, European Journal of Organic Chemistry, 2011(27), pp. 5255-5260. https://doi.org/10.1002/ejoc.201100783
APA Citation style: Zheng, P., Cai, Z., A, G., Rooshenas, P., Schreiner, P., & Harmata, M. (2011). Carbon‐to‐Carbon Anion Relay Chemistry: Facile Generation of Substituted Allyllithium Species. European Journal of Organic Chemistry. 2011(27), 5255-5260. https://doi.org/10.1002/ejoc.201100783
