Journalartikel

Diamondoid Phosphines – Selective Phosphorylation of Nanodiamonds


AutorenlisteSchwertfeger, H; Machuy, MM; Würtele, C; Dahl, JEP; Carlson, RMK; Schreiner, PR

Jahr der Veröffentlichung2010

Seiten609-615

ZeitschriftAdvanced Synthesis & Catalysis

Bandnummer352

Heftnummer4

DOI Linkhttps://doi.org/10.1002/adsc.200900774

VerlagWiley


Abstract

The diamondoids (nanodiamonds) diamantane and triamantane were
selectively converted into diorganophosphinic acid chlorides by reacting
them with phosphorus trichloride under Friedel–Crafts‐like conditions.
The di‐diamondoid phosphinic acid chlorides were subsequently reduced
with trichlorosilane to give the hitherto unknown corresponding
di‐diamondoid phosphines. These diamondoid phosphinic acid chlorides and
phosphines are of great utility as starting materials in organo‐element
and coordination chemistry due to their extraordinary rigidity and
steric bulk.




Zitierstile

Harvard-ZitierstilSchwertfeger, H., Machuy, M., Würtele, C., Dahl, J., Carlson, R. and Schreiner, P. (2010) Diamondoid Phosphines – Selective Phosphorylation of Nanodiamonds, Advanced Synthesis & Catalysis, 352(4), pp. 609-615. https://doi.org/10.1002/adsc.200900774

APA-ZitierstilSchwertfeger, H., Machuy, M., Würtele, C., Dahl, J., Carlson, R., & Schreiner, P. (2010). Diamondoid Phosphines – Selective Phosphorylation of Nanodiamonds. Advanced Synthesis & Catalysis. 352(4), 609-615. https://doi.org/10.1002/adsc.200900774



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