Journal article

Diamondoid Phosphines – Selective Phosphorylation of Nanodiamonds


Authors listSchwertfeger, H; Machuy, MM; Würtele, C; Dahl, JEP; Carlson, RMK; Schreiner, PR

Publication year2010

Pages609-615

JournalAdvanced Synthesis & Catalysis

Volume number352

Issue number4

DOI Linkhttps://doi.org/10.1002/adsc.200900774

PublisherWiley


Abstract

The diamondoids (nanodiamonds) diamantane and triamantane were
selectively converted into diorganophosphinic acid chlorides by reacting
them with phosphorus trichloride under Friedel–Crafts‐like conditions.
The di‐diamondoid phosphinic acid chlorides were subsequently reduced
with trichlorosilane to give the hitherto unknown corresponding
di‐diamondoid phosphines. These diamondoid phosphinic acid chlorides and
phosphines are of great utility as starting materials in organo‐element
and coordination chemistry due to their extraordinary rigidity and
steric bulk.




Citation Styles

Harvard Citation styleSchwertfeger, H., Machuy, M., Würtele, C., Dahl, J., Carlson, R. and Schreiner, P. (2010) Diamondoid Phosphines – Selective Phosphorylation of Nanodiamonds, Advanced Synthesis & Catalysis, 352(4), pp. 609-615. https://doi.org/10.1002/adsc.200900774

APA Citation styleSchwertfeger, H., Machuy, M., Würtele, C., Dahl, J., Carlson, R., & Schreiner, P. (2010). Diamondoid Phosphines – Selective Phosphorylation of Nanodiamonds. Advanced Synthesis & Catalysis. 352(4), 609-615. https://doi.org/10.1002/adsc.200900774


Last updated on 2025-21-05 at 13:31