Journal article
Authors list: Schwertfeger, H; Machuy, MM; Würtele, C; Dahl, JEP; Carlson, RMK; Schreiner, PR
Publication year: 2010
Pages: 609-615
Journal: Advanced Synthesis & Catalysis
Volume number: 352
Issue number: 4
DOI Link: https://doi.org/10.1002/adsc.200900774
Publisher: Wiley
The diamondoids (nanodiamonds) diamantane and triamantane were
Abstract:
selectively converted into diorganophosphinic acid chlorides by reacting
them with phosphorus trichloride under Friedel–Crafts‐like conditions.
The di‐diamondoid phosphinic acid chlorides were subsequently reduced
with trichlorosilane to give the hitherto unknown corresponding
di‐diamondoid phosphines. These diamondoid phosphinic acid chlorides and
phosphines are of great utility as starting materials in organo‐element
and coordination chemistry due to their extraordinary rigidity and
steric bulk.
Citation Styles
Harvard Citation style: Schwertfeger, H., Machuy, M., Würtele, C., Dahl, J., Carlson, R. and Schreiner, P. (2010) Diamondoid Phosphines – Selective Phosphorylation of Nanodiamonds, Advanced Synthesis & Catalysis, 352(4), pp. 609-615. https://doi.org/10.1002/adsc.200900774
APA Citation style: Schwertfeger, H., Machuy, M., Würtele, C., Dahl, J., Carlson, R., & Schreiner, P. (2010). Diamondoid Phosphines – Selective Phosphorylation of Nanodiamonds. Advanced Synthesis & Catalysis. 352(4), 609-615. https://doi.org/10.1002/adsc.200900774