Journalartikel

Hydroxy Derivatives of Diamantane, Triamantane, and [121]Tetramantane: Selective Preparation of Bis‐Apical Derivatives


AutorenlisteFokina, NA; Tkachenko, BA; Merz, A; Serafin, M; Dahl, JEP; Carlson, RMK; Fokin, AA; Schreiner, PR

Jahr der Veröffentlichung2007

Seiten4738-4745

ZeitschriftEuropean Journal of Organic Chemistry

Bandnummer2007

Heftnummer28

DOI Linkhttps://doi.org/10.1002/ejoc.200700378

VerlagWiley


Abstract

Functionalizations of diamantane, triamantane, and tetramantane with electrophilic reagents (Br2,
nitric acid) lead to various apical and medial disubstituted products
that were separated and characterized individually. The highly desirable
and otherwise inaccessible thermodynamically more stable apical
bis‐derivatives were obtained with high preparative yields through acid
catalyzed isomerizations.




Zitierstile

Harvard-ZitierstilFokina, N., Tkachenko, B., Merz, A., Serafin, M., Dahl, J., Carlson, R., et al. (2007) Hydroxy Derivatives of Diamantane, Triamantane, and [121]Tetramantane: Selective Preparation of Bis‐Apical Derivatives, European Journal of Organic Chemistry, 2007(28), pp. 4738-4745. https://doi.org/10.1002/ejoc.200700378

APA-ZitierstilFokina, N., Tkachenko, B., Merz, A., Serafin, M., Dahl, J., Carlson, R., Fokin, A., & Schreiner, P. (2007). Hydroxy Derivatives of Diamantane, Triamantane, and [121]Tetramantane: Selective Preparation of Bis‐Apical Derivatives. European Journal of Organic Chemistry. 2007(28), 4738-4745. https://doi.org/10.1002/ejoc.200700378



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