Hydroxy Derivatives of Diamantane, Triamantane, and [121]Tetramantane: Selective Preparation of Bis‐Apical Derivatives - Research portal of Justus Liebig University Giessen:

Journal article

Hydroxy Derivatives of Diamantane, Triamantane, and [121]Tetramantane: Selective Preparation of Bis‐Apical Derivatives

Authors list: Fokina, NA; Tkachenko, BA; Merz, A; Serafin, M; Dahl, JEP; Carlson, RMK; Fokin, AA; Schreiner, PR

Publication year: 2007

Pages: 4738-4745

Journal: European Journal of Organic Chemistry

Volume number: 2007

Issue number: 28

DOI Link: https://doi.org/10.1002/ejoc.200700378

Publisher: Wiley

Abstract:

Functionalizations of diamantane, triamantane, and tetramantane with electrophilic reagents (Br₂,
nitric acid) lead to various apical and medial disubstituted products
that were separated and characterized individually. The highly desirable
and otherwise inaccessible thermodynamically more stable apical
bis‐derivatives were obtained with high preparative yields through acid
catalyzed isomerizations.

Authors/Editors

- Uni.-Prof. Dr. Peter Richard Schreiner, PhD

Citation Styles

Harvard Citation style: Fokina, N., Tkachenko, B., Merz, A., Serafin, M., Dahl, J., Carlson, R., et al. (2007) Hydroxy Derivatives of Diamantane, Triamantane, and [121]Tetramantane: Selective Preparation of Bis‐Apical Derivatives, European Journal of Organic Chemistry, 2007(28), pp. 4738-4745. https://doi.org/10.1002/ejoc.200700378

APA Citation style: Fokina, N., Tkachenko, B., Merz, A., Serafin, M., Dahl, J., Carlson, R., Fokin, A., & Schreiner, P. (2007). Hydroxy Derivatives of Diamantane, Triamantane, and [121]Tetramantane: Selective Preparation of Bis‐Apical Derivatives. European Journal of Organic Chemistry. 2007(28), 4738-4745. https://doi.org/10.1002/ejoc.200700378

SDG Areas

7 Affordable and clean energy