Journalartikel

Synthesis of hierarchically porous carbon monoliths with highly ordered microstructure and their application in rechargeable lithium batteries with high-rate capability


AutorenlisteHu, YS; Adelhelm, P; Smarsly, BM; Hore, S; Antonietti, M; Maier, J

Jahr der Veröffentlichung2007

Seiten1873-1878

ZeitschriftAdvanced Functional Materials

Bandnummer17

Heftnummer12

ISSN1616-301X

DOI Linkhttps://doi.org/10.1002/adfm.200601152

VerlagWiley


Abstract
In this paper, we report on Li storage in hierarchically porous carbon monoliths with a relatively higher graphite-like ordered carbon structure. Macroscopic carbon monoliths with both mesopores and macropores were successfully prepared by using meso-/macroporous silica as a template and using mesophase pitch as a precursor. Owing to the high porosity (providing ionic transport channels) and high electronic conductivity (ca. 0.1 S cm(-1)), this porous carbon monolith with a mixed conducting 3D network shows a superior high-rate performance if used as anode material in electrochemical lithium cells. A challenge for future research as to its applicability in batteries is the lowering of the irreversible capacity.



Zitierstile

Harvard-ZitierstilHu, Y., Adelhelm, P., Smarsly, B., Hore, S., Antonietti, M. and Maier, J. (2007) Synthesis of hierarchically porous carbon monoliths with highly ordered microstructure and their application in rechargeable lithium batteries with high-rate capability, Advanced Functional Materials, 17(12), pp. 1873-1878. https://doi.org/10.1002/adfm.200601152

APA-ZitierstilHu, Y., Adelhelm, P., Smarsly, B., Hore, S., Antonietti, M., & Maier, J. (2007). Synthesis of hierarchically porous carbon monoliths with highly ordered microstructure and their application in rechargeable lithium batteries with high-rate capability. Advanced Functional Materials. 17(12), 1873-1878. https://doi.org/10.1002/adfm.200601152


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