Journal article

Synthesis of hierarchically porous carbon monoliths with highly ordered microstructure and their application in rechargeable lithium batteries with high-rate capability


Authors listHu, YS; Adelhelm, P; Smarsly, BM; Hore, S; Antonietti, M; Maier, J

Publication year2007

Pages1873-1878

JournalAdvanced Functional Materials

Volume number17

Issue number12

ISSN1616-301X

DOI Linkhttps://doi.org/10.1002/adfm.200601152

PublisherWiley


Abstract
In this paper, we report on Li storage in hierarchically porous carbon monoliths with a relatively higher graphite-like ordered carbon structure. Macroscopic carbon monoliths with both mesopores and macropores were successfully prepared by using meso-/macroporous silica as a template and using mesophase pitch as a precursor. Owing to the high porosity (providing ionic transport channels) and high electronic conductivity (ca. 0.1 S cm(-1)), this porous carbon monolith with a mixed conducting 3D network shows a superior high-rate performance if used as anode material in electrochemical lithium cells. A challenge for future research as to its applicability in batteries is the lowering of the irreversible capacity.



Citation Styles

Harvard Citation styleHu, Y., Adelhelm, P., Smarsly, B., Hore, S., Antonietti, M. and Maier, J. (2007) Synthesis of hierarchically porous carbon monoliths with highly ordered microstructure and their application in rechargeable lithium batteries with high-rate capability, Advanced Functional Materials, 17(12), pp. 1873-1878. https://doi.org/10.1002/adfm.200601152

APA Citation styleHu, Y., Adelhelm, P., Smarsly, B., Hore, S., Antonietti, M., & Maier, J. (2007). Synthesis of hierarchically porous carbon monoliths with highly ordered microstructure and their application in rechargeable lithium batteries with high-rate capability. Advanced Functional Materials. 17(12), 1873-1878. https://doi.org/10.1002/adfm.200601152


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