Journal article

Reactions of a copper(II) superoxo complex lead to C-H and O-H substrate oxygenation : modeling copper-monooxygenase C-H hydroxylation


Authors list: Maiti, D; Lee, DH; Gaoutchenova, K; Würtele, C; Holthausen, MC; Sarjeant, AA; Sundermeyer, J; Schindler, S; Karlin, KD

Publication year: 2008

Pages: 82-85

Journal: Angewandte Chemie International Edition

Volume number: 47

Issue number: 1

ISSN: 1433-7851

DOI Link: https://doi.org/10.1002/anie.200704389

Publisher: Wiley


Abstract: 

Donor makes the difference: The mononuclear η1‐superoxo copper(II) complex 1 undergoes dioxygen activation with the addition of hydrogen‐atom donors. Net O2‐derived O‐atom insertion into the N‐methyl group of the ligand leads to formation of a copper(II)‐alkoxide product 2. The cupric superoxo species 1 itself is not capable of the observed hydroxylation reaction.




Citation Styles

Harvard Citation style: Maiti, D., Lee, D., Gaoutchenova, K., Würtele, C., Holthausen, M., Sarjeant, A., et al. (2008) Reactions of a copper(II) superoxo complex lead to C-H and O-H substrate oxygenation : modeling copper-monooxygenase C-H hydroxylation, Angewandte Chemie International Edition, 47(1), pp. 82-85. https://doi.org/10.1002/anie.200704389

APA Citation style: Maiti, D., Lee, D., Gaoutchenova, K., Würtele, C., Holthausen, M., Sarjeant, A., Sundermeyer, J., Schindler, S., & Karlin, K. (2008). Reactions of a copper(II) superoxo complex lead to C-H and O-H substrate oxygenation : modeling copper-monooxygenase C-H hydroxylation. Angewandte Chemie International Edition. 47(1), 82-85. https://doi.org/10.1002/anie.200704389


Last updated on 2025-21-05 at 13:58