Secondary Phosphine Oxide Preligands for Palladium‐Catalyzed C–H (Hetero)Arylations: Efficient Access to Pybox Ligands - Forschungsportal der Justus-Liebig-Universität Gießen:

Journalartikel

Secondary Phosphine Oxide Preligands for Palladium‐Catalyzed C–H (Hetero)Arylations: Efficient Access to Pybox Ligands

Autorenliste: Ghorai, D; Müller, V; Keil, H; Stalke, D; Zanoni, G; Tkachenko, BA; Schreiner, PR; Ackermann, L

Jahr der Veröffentlichung: 2017

Seiten: 3137-3141

Zeitschrift: Advanced Synthesis & Catalysis

Bandnummer: 359

Heftnummer: 18

DOI Link: https://doi.org/10.1002/adsc.201700663

Verlag: Wiley

Abstract:

C–H arylations of oxazolines were accomplished with a well‐defined palladium catalyst derived from a secondary bisdiamantyl phosphine oxide. The single‐component secondary phosphine oxide (SPO)‐palladium complex enabled C–H activations with aryl bromides and challenging aryl chlorides in the absence of directing groups, setting the stage for the step‐economical synthesis of pybox ligands under racemization‐free reaction conditions.

Autoren/Herausgeber

- Uni.-Prof. Dr. Peter Richard Schreiner, PhD

Zitierstile

Harvard-Zitierstil: Ghorai, D., Müller, V., Keil, H., Stalke, D., Zanoni, G., Tkachenko, B., et al. (2017) Secondary Phosphine Oxide Preligands for Palladium‐Catalyzed C–H (Hetero)Arylations: Efficient Access to Pybox Ligands, Advanced Synthesis & Catalysis, 359(18), pp. 3137-3141. https://doi.org/10.1002/adsc.201700663

APA-Zitierstil: Ghorai, D., Müller, V., Keil, H., Stalke, D., Zanoni, G., Tkachenko, B., Schreiner, P., & Ackermann, L. (2017). Secondary Phosphine Oxide Preligands for Palladium‐Catalyzed C–H (Hetero)Arylations: Efficient Access to Pybox Ligands. Advanced Synthesis & Catalysis. 359(18), 3137-3141. https://doi.org/10.1002/adsc.201700663