Secondary Phosphine Oxide Preligands for Palladium‐Catalyzed C–H (Hetero)Arylations: Efficient Access to Pybox Ligands - Research portal of Justus Liebig University Giessen:

Journal article

Secondary Phosphine Oxide Preligands for Palladium‐Catalyzed C–H (Hetero)Arylations: Efficient Access to Pybox Ligands

Authors list: Ghorai, D; Müller, V; Keil, H; Stalke, D; Zanoni, G; Tkachenko, BA; Schreiner, PR; Ackermann, L

Publication year: 2017

Pages: 3137-3141

Journal: Advanced Synthesis & Catalysis

Volume number: 359

Issue number: 18

DOI Link: https://doi.org/10.1002/adsc.201700663

Publisher: Wiley

Abstract:

C–H arylations of oxazolines were accomplished with a well‐defined palladium catalyst derived from a secondary bisdiamantyl phosphine oxide. The single‐component secondary phosphine oxide (SPO)‐palladium complex enabled C–H activations with aryl bromides and challenging aryl chlorides in the absence of directing groups, setting the stage for the step‐economical synthesis of pybox ligands under racemization‐free reaction conditions.

Authors/Editors

- Uni.-Prof. Dr. Peter Richard Schreiner, PhD

Citation Styles

Harvard Citation style: Ghorai, D., Müller, V., Keil, H., Stalke, D., Zanoni, G., Tkachenko, B., et al. (2017) Secondary Phosphine Oxide Preligands for Palladium‐Catalyzed C–H (Hetero)Arylations: Efficient Access to Pybox Ligands, Advanced Synthesis & Catalysis, 359(18), pp. 3137-3141. https://doi.org/10.1002/adsc.201700663

APA Citation style: Ghorai, D., Müller, V., Keil, H., Stalke, D., Zanoni, G., Tkachenko, B., Schreiner, P., & Ackermann, L. (2017). Secondary Phosphine Oxide Preligands for Palladium‐Catalyzed C–H (Hetero)Arylations: Efficient Access to Pybox Ligands. Advanced Synthesis & Catalysis. 359(18), 3137-3141. https://doi.org/10.1002/adsc.201700663