Generation and characterization of the phenylthiyl radical and its oxidation to the phenylthiylperoxy and phenylsulfonyl radicals - Forschungsportal der Justus-Liebig-Universität Gießen:

Journalartikel

Generation and characterization of the phenylthiyl radical and its oxidation to the phenylthiylperoxy and phenylsulfonyl radicals

Autorenliste: Mardyukov, A; Schreiner, PR

Jahr der Veröffentlichung: 2016

Seiten: 26161-26165

Zeitschrift: Physical Chemistry Chemical Physics

Bandnummer: 18

Heftnummer: 37

Open Access Status: Hybrid

DOI Link: https://doi.org/10.1039/C6CP04278C

Verlag: Royal Society of Chemistry

Abstract:

The phenylthiyl radical (1) was prepared in the gas
phase by vacuum flash pyrolysis of allylphenyl sulfide or diphenyl
sulfide and isolated in an argon matrix. The hitherto unknown
phenylthiyl peroxy radical was synthesized by co-condensation of 1 with molecular oxygen. Irradiation with light of λ = 465 nm led to a rearrangement to the novel phenylsulfonyl radical.

Autoren/Herausgeber

- Uni.-Prof. Dr. Peter Richard Schreiner, PhD

Zitierstile

Harvard-Zitierstil: Mardyukov, A. and Schreiner, P. (2016) Generation and characterization of the phenylthiyl radical and its oxidation to the phenylthiylperoxy and phenylsulfonyl radicals, Physical Chemistry Chemical Physics, 18(37), pp. 26161-26165. https://doi.org/10.1039/C6CP04278C

APA-Zitierstil: Mardyukov, A., & Schreiner, P. (2016). Generation and characterization of the phenylthiyl radical and its oxidation to the phenylthiylperoxy and phenylsulfonyl radicals. Physical Chemistry Chemical Physics. 18(37), 26161-26165. https://doi.org/10.1039/C6CP04278C