Generation and characterization of the phenylthiyl radical and its oxidation to the phenylthiylperoxy and phenylsulfonyl radicals - Research portal of Justus Liebig University Giessen:

Journal article

Generation and characterization of the phenylthiyl radical and its oxidation to the phenylthiylperoxy and phenylsulfonyl radicals

Authors list: Mardyukov, A; Schreiner, PR

Publication year: 2016

Pages: 26161-26165

Journal: Physical Chemistry Chemical Physics

Volume number: 18

Issue number: 37

Open access status: Hybrid

DOI Link: https://doi.org/10.1039/C6CP04278C

Publisher: Royal Society of Chemistry

Abstract:

The phenylthiyl radical (1) was prepared in the gas
phase by vacuum flash pyrolysis of allylphenyl sulfide or diphenyl
sulfide and isolated in an argon matrix. The hitherto unknown
phenylthiyl peroxy radical was synthesized by co-condensation of 1 with molecular oxygen. Irradiation with light of λ = 465 nm led to a rearrangement to the novel phenylsulfonyl radical.

Authors/Editors

- Uni.-Prof. Dr. Peter Richard Schreiner, PhD

Citation Styles

Harvard Citation style: Mardyukov, A. and Schreiner, P. (2016) Generation and characterization of the phenylthiyl radical and its oxidation to the phenylthiylperoxy and phenylsulfonyl radicals, Physical Chemistry Chemical Physics, 18(37), pp. 26161-26165. https://doi.org/10.1039/C6CP04278C

APA Citation style: Mardyukov, A., & Schreiner, P. (2016). Generation and characterization of the phenylthiyl radical and its oxidation to the phenylthiylperoxy and phenylsulfonyl radicals. Physical Chemistry Chemical Physics. 18(37), 26161-26165. https://doi.org/10.1039/C6CP04278C