Journalartikel
Autorenliste: de Meijere, A; Khlebnikov, AF; Kozhushkov, SI; Miyazawa, K; Frank, D; Schreiner, PR; Rinderspacher, BC; Yufit, DS; Howard, JAK
Jahr der Veröffentlichung: 2004
Seiten: 6553-6557
Zeitschrift: Angewandte Chemie International Edition
Bandnummer: 43
Heftnummer: 47
ISSN: 1433-7851
DOI Link: https://doi.org/10.1002/anie.200461166
Verlag: Wiley
Remarkably high specific rotations, even at 589 nm, are exhibited by the enantiomerically pure σ‐[9]helicenes (M)‐(−)‐ and (P)‐(+)‐[9]triangulanes
Abstract:
(see scheme). This significant power of rotation, which is in very good
agreement with calculated values, must be attributed to the rigid
helical framework of σ bonds in these formally saturated hydrocarbons.
Zitierstile
Harvard-Zitierstil: de Meijere, A., Khlebnikov, A., Kozhushkov, S., Miyazawa, K., Frank, D., Schreiner, P., et al. (2004) A convergent route to enantiomerically pure higher [n-2]triangulanedimethanol derivatives and [n]triangulanes (n >= 7), Angewandte Chemie International Edition, 43(47), pp. 6553-6557. https://doi.org/10.1002/anie.200461166
APA-Zitierstil: de Meijere, A., Khlebnikov, A., Kozhushkov, S., Miyazawa, K., Frank, D., Schreiner, P., Rinderspacher, B., Yufit, D., & Howard, J. (2004). A convergent route to enantiomerically pure higher [n-2]triangulanedimethanol derivatives and [n]triangulanes (n >= 7). Angewandte Chemie International Edition. 43(47), 6553-6557. https://doi.org/10.1002/anie.200461166
