Journal article

A convergent route to enantiomerically pure higher [n-2]triangulanedimethanol derivatives and [n]triangulanes (n >= 7)


Authors listde Meijere, A; Khlebnikov, AF; Kozhushkov, SI; Miyazawa, K; Frank, D; Schreiner, PR; Rinderspacher, BC; Yufit, DS; Howard, JAK

Publication year2004

Pages6553-6557

JournalAngewandte Chemie International Edition

Volume number43

Issue number47

ISSN1433-7851

DOI Linkhttps://doi.org/10.1002/anie.200461166

PublisherWiley


Abstract

Remarkably high specific rotations, even at 589 nm, are exhibited by the enantiomerically pure σ‐[9]helicenes (M)‐(−)‐ and (P)‐(+)‐[9]triangulanes
(see scheme). This significant power of rotation, which is in very good
agreement with calculated values, must be attributed to the rigid
helical framework of σ bonds in these formally saturated hydrocarbons.




Citation Styles

Harvard Citation stylede Meijere, A., Khlebnikov, A., Kozhushkov, S., Miyazawa, K., Frank, D., Schreiner, P., et al. (2004) A convergent route to enantiomerically pure higher [n-2]triangulanedimethanol derivatives and [n]triangulanes (n >= 7), Angewandte Chemie International Edition, 43(47), pp. 6553-6557. https://doi.org/10.1002/anie.200461166

APA Citation stylede Meijere, A., Khlebnikov, A., Kozhushkov, S., Miyazawa, K., Frank, D., Schreiner, P., Rinderspacher, B., Yufit, D., & Howard, J. (2004). A convergent route to enantiomerically pure higher [n-2]triangulanedimethanol derivatives and [n]triangulanes (n >= 7). Angewandte Chemie International Edition. 43(47), 6553-6557. https://doi.org/10.1002/anie.200461166


Last updated on 2025-21-05 at 14:59