Conference paper

The Generation of Mesoporous CeO2 With Crystalline Pore Walls Using Novel Block Copolymers


Authors listBrezesinski, T; Smarsly, B; Groenewolt, M; Antonietti, M; Grosso, D; Boissiere, C; Sanchez, C

Appeared inNanoporous materials IV

Editor listSayari, A; Jaroniec, M

Publication year2005

Pages243-248

ISBN0-444-51748-0

DOI Linkhttps://doi.org/10.1016/S0167-2991(05)80214-9

Conference4th International Symposium on Nanoporous Materials

Title of seriesStudies in surface science and catalysis

Number in series156


Abstract
Mesoporous thin films of cerium oxide with spherical pores and crystalline pore walls were prepared using evaporation-induced self-assembly (EISA), taking advantage of a novel type of block copolymer. The films were characterized by various techniques, in particular transmission electron microscopy (TEM), atomic force microscopy (AFM), small-angle x-ray scattering (SAXS), wide-angle x-ray scattering (WAXS) and krypton/nitrogen sorption. The evaluation of the SAXS data allowed for a quantification of the pore dimension perpendicular to the film and revealed a significant degree of deformation of the pores during calcination. Detailed WAXS studies as a function of the temperature showed that the crystallite size can be finely tuned as a function of the heat treatment.



Citation Styles

Harvard Citation styleBrezesinski, T., Smarsly, B., Groenewolt, M., Antonietti, M., Grosso, D., Boissiere, C., et al. (2005) The Generation of Mesoporous CeO2 With Crystalline Pore Walls Using Novel Block Copolymers, in Sayari, A. and Jaroniec, M. (eds.) Nanoporous materials IV. Amsterdam: Elsevier. pp. 243-248. https://doi.org/10.1016/S0167-2991(05)80214-9

APA Citation styleBrezesinski, T., Smarsly, B., Groenewolt, M., Antonietti, M., Grosso, D., Boissiere, C., & Sanchez, C. (2005). The Generation of Mesoporous CeO2 With Crystalline Pore Walls Using Novel Block Copolymers. In Sayari, A., & Jaroniec, M. (Eds.), Nanoporous materials IV. (pp. 243-248). Elsevier. https://doi.org/10.1016/S0167-2991(05)80214-9


Last updated on 2025-21-05 at 15:01