Journalartikel
Autorenliste: Moncea, O; Gunawan, MA; Poinsot, D; Cattey, H; Becker, J; Yurchenko, RI; Butova, ED; Hausmann, H; Sekutor, M; Fokin, AA; Hierso, JC; Schreiner, PR
Jahr der Veröffentlichung: 2016
Seiten: 8759-8769
Zeitschrift: The Journal of Organic Chemistry
Bandnummer: 81
Heftnummer: 19
Open Access Status: Green
DOI Link: https://doi.org/10.1021/acs.joc.6b01219
Verlag: American Chemical Society
Direct unequal C–H bond difunctionalization of phosphorylated diamantane
Abstract:
was achieved in high yield from the corresponding phosphonates.
Reduction of the functionalized phosphonates provides access to novel
primary and secondary alkyl/aryl diamantane phosphines. The prepared
primary diamantyl phosphines are quite air stable compared to their
adamantyl and especially alkyl or aryl analogues. This finding is
corroborated by comparing the singly occupied molecular orbital energy
levels of the corresponding phosphine radical cations obtained by
density functional theory computations.
Zitierstile
Harvard-Zitierstil: Moncea, O., Gunawan, M., Poinsot, D., Cattey, H., Becker, J., Yurchenko, R., et al. (2016) Defying Stereotypes with Nanodiamonds: Stable Primary Diamondoid Phosphines, The Journal of Organic Chemistry, 81(19), pp. 8759-8769. https://doi.org/10.1021/acs.joc.6b01219
APA-Zitierstil: Moncea, O., Gunawan, M., Poinsot, D., Cattey, H., Becker, J., Yurchenko, R., Butova, E., Hausmann, H., Sekutor, M., Fokin, A., Hierso, J., & Schreiner, P. (2016). Defying Stereotypes with Nanodiamonds: Stable Primary Diamondoid Phosphines. The Journal of Organic Chemistry. 81(19), 8759-8769. https://doi.org/10.1021/acs.joc.6b01219