Journalartikel

Selective Preparation of Diamondoid Phosphonates


AutorenlisteFokin, AA; Yurchenko, RI; Tkachenko, BA; Fokina, NA; Gunawan, MA; Poinsot, D; Dahl, JEP; Carlson, RMK; Serafin, M; Cattey, H; Hierso, JC; Schreiner, PR

Jahr der Veröffentlichung2014

Seiten5369-5373

ZeitschriftThe Journal of Organic Chemistry

Bandnummer79

Heftnummer11

DOI Linkhttps://doi.org/10.1021/jo500793m

VerlagAmerican Chemical Society


Abstract

We present an effective sequence for the preparation of phosphonic acid
derivatives of the diamondoids diamantane, triamantane,
[121]tetramantane, and [1(2,3)4]pentamantane. The reactions of the
corresponding diamondoid hydroxy derivatives with PCl3 in sulfuric or trifluoroacetic acid give mono- as well as didichlorophosphorylated diamondoids in high preparative yields.




Zitierstile

Harvard-ZitierstilFokin, A., Yurchenko, R., Tkachenko, B., Fokina, N., Gunawan, M., Poinsot, D., et al. (2014) Selective Preparation of Diamondoid Phosphonates, The Journal of Organic Chemistry, 79(11), pp. 5369-5373. https://doi.org/10.1021/jo500793m

APA-ZitierstilFokin, A., Yurchenko, R., Tkachenko, B., Fokina, N., Gunawan, M., Poinsot, D., Dahl, J., Carlson, R., Serafin, M., Cattey, H., Hierso, J., & Schreiner, P. (2014). Selective Preparation of Diamondoid Phosphonates. The Journal of Organic Chemistry. 79(11), 5369-5373. https://doi.org/10.1021/jo500793m



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