Journal article

Selective Preparation of Diamondoid Phosphonates


Authors listFokin, AA; Yurchenko, RI; Tkachenko, BA; Fokina, NA; Gunawan, MA; Poinsot, D; Dahl, JEP; Carlson, RMK; Serafin, M; Cattey, H; Hierso, JC; Schreiner, PR

Publication year2014

Pages5369-5373

JournalThe Journal of Organic Chemistry

Volume number79

Issue number11

DOI Linkhttps://doi.org/10.1021/jo500793m

PublisherAmerican Chemical Society


Abstract

We present an effective sequence for the preparation of phosphonic acid
derivatives of the diamondoids diamantane, triamantane,
[121]tetramantane, and [1(2,3)4]pentamantane. The reactions of the
corresponding diamondoid hydroxy derivatives with PCl3 in sulfuric or trifluoroacetic acid give mono- as well as didichlorophosphorylated diamondoids in high preparative yields.




Citation Styles

Harvard Citation styleFokin, A., Yurchenko, R., Tkachenko, B., Fokina, N., Gunawan, M., Poinsot, D., et al. (2014) Selective Preparation of Diamondoid Phosphonates, The Journal of Organic Chemistry, 79(11), pp. 5369-5373. https://doi.org/10.1021/jo500793m

APA Citation styleFokin, A., Yurchenko, R., Tkachenko, B., Fokina, N., Gunawan, M., Poinsot, D., Dahl, J., Carlson, R., Serafin, M., Cattey, H., Hierso, J., & Schreiner, P. (2014). Selective Preparation of Diamondoid Phosphonates. The Journal of Organic Chemistry. 79(11), 5369-5373. https://doi.org/10.1021/jo500793m


Last updated on 2025-21-05 at 15:21