Exploration of 1,2-phenylenediboronic esters as potential bidentate catalysts for organic synthesis - Forschungsportal der Justus-Liebig-Universität Gießen:

Journalartikel

Exploration of 1,2-phenylenediboronic esters as potential bidentate catalysts for organic synthesis

Autorenliste: Bader, SL; Kessler, SN; Zampese, JA; Wegner, HA

Jahr der Veröffentlichung: 2013

Seiten: 531-537

Zeitschrift: Monatshefte für Chemie - Chemical Monthly

Bandnummer: 144

Heftnummer: 4

ISSN: 0026-9247

DOI Link: https://doi.org/10.1007/s00706-012-0898-y

Verlag: Springer

Abstract:
Recently, we described the first inverse electron demand Diels-Alder reaction of 1,2-diazene catalyzed by a bidentate Lewis acid. Herein we investigate 1,2-phenylenediboronic esters as potential catalysts for this transformation offering higher stability and easier handling than the currently used boranthracene derivatives. Different 1,2-phenylenediboronic esters were prepared and their ability to form bidentate coordination complexes with phthalazine was analyzed. Although a 1:1 complex was observed, X-ray analysis revealed binding only in a monodentate fashion.

Autoren/Herausgeber

- Uni.-Prof. Dr. Hermann Andreas Wegner

Zitierstile

Harvard-Zitierstil: Bader, S., Kessler, S., Zampese, J. and Wegner, H. (2013) Exploration of 1,2-phenylenediboronic esters as potential bidentate catalysts for organic synthesis, Monatshefte für Chemie - Chemical Monthly, 144(4), pp. 531-537. https://doi.org/10.1007/s00706-012-0898-y

APA-Zitierstil: Bader, S., Kessler, S., Zampese, J., & Wegner, H. (2013). Exploration of 1,2-phenylenediboronic esters as potential bidentate catalysts for organic synthesis. Monatshefte für Chemie - Chemical Monthly. 144(4), 531-537. https://doi.org/10.1007/s00706-012-0898-y